| Autor: |
Alferova, S. I., Kisin, A. V., Kudryavtseva, G. A., Zalukaev, L. P., Parnes, Z. P. |
| Zdroj: |
Russian Chemical Bulletin; October 1982, Vol. 31 Issue: 10 p2057-2060, 4p |
| Abstrakt: |
Conclusions 1.1-Phthaloyl-2-p-X-substituted benzoylcyclopropanes (where X=F, Cl, Br, OCH3), regardless of the substituent, are selectively reduced by ionic hydrogenation to 1-phthaloyl-2-p-substituted benzylcyclopropanes. As the electronegativity of the substituent decreases, the reduction rate increases.2.The stability of the phthaloyl CO groups and the three-membered ring in this reaction is attributed to their mutual interaction; this agrees well with experimental data and with the13C NMR spectra of the compounds. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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