Oxidative addition products in reactions of heteroorganic compounds with substituted o-quinones

Autor: Razuvaev, G. A., Abakumov, G. A., Gladyshev, E. N., Bayushkin, P. Ya., Tsaryapkin, V. A.
Zdroj: Russian Chemical Bulletin; September 1982, Vol. 31 Issue: 9 p1888-1893, 6p
Abstrakt: 1.The products of the oxidative 1,4-addition formed in the reaction of diheteroorganic compounds with sterically hindered o-quinones react readily with organic oxidants.2.The types of reactions of o-hemiquinolates of Group IVB elements are determined by the tendency to eliminate alkyl and aryl groups from the heteroatom under the influence of the unpaired electron of the free-radical ligand.
Databáze: Supplemental Index