Magnetic isotope effect and enrichment of oxygen in17O isotope in chain oxidation reaction. 2. Kinetics

Autor: Belyakov, V. A., Mal'tsev, V. I., Buchachenko, A. L.
Zdroj: Russian Chemical Bulletin; May 1982, Vol. 31 Issue: 5 p906-913, 8p
Abstrakt: 1.A kinetic theory is given for the enrichment of molecular oxygen in17O isotope in hydrocarbon oxidation chain reactions. Kinetic equations have been derived for the isotope composition of the oxygen in relation to the conversion with respect to oxygen, the length of the kinetic chain, and the magnetic isotope effect.2.Kinetic regimes for maximal isotope enrichment have been predicted.
Databáze: Supplemental Index