Stereochemistry of reaction of diethylamine with diacetylene

Autor: Volkov, A. N., Vavilova, A. N., Sokolyanskaya, L. V., Sigalov, M. V.
Zdroj: Russian Chemical Bulletin; March 1982, Vol. 31 Issue: 3 p613-615, 3p
Abstrakt: 1.The stereochemistry of the reaction of diethylamine with diacetylene depends on the nature of the solvent and the temperature.2.The formation of a mixture of the cis and trans isomers is caused by a difference in protonating the transition state and is amenable to both thermodynamic and kinetic control.
Databáze: Supplemental Index