Diastereoselective hydrogenation of N-acetyldehydrodipeptides

Autor: Latov, V. K., Vinogradova, A. I., Saporovskaya, M. B., Belikov, V. M.
Zdroj: Russian Chemical Bulletin; March 1982, Vol. 31 Issue: 3 p609-612, 4p
Abstrakt: 1.Feasibility was demonstrated for the hydrogenation of linear N-acetyldehydrophenylalanyl dipeptides over achiral catalysts with high degrees of asymmetric induction.2.High and, in some cases, quantitative asymmetric yields of both S- and R-phenylalanine were obtained as a result of the hydrogenation of N-acetyldehydrophenylalanylglutamic acid and N-acetyldehydrophenylalanylphenylalanine with subsequent hydrolysis of the dipeptide.
Databáze: Supplemental Index