Preparation and structure of 2-acetyl-2,3-epoxycarane

Autor: Ibragimova, N. D., Vul'fson, S. G., Donskova, A. I., Bikeev, Sh. S., Vereshchagin, A. N., Samitov, Yu. Yu.
Zdroj: Russian Chemical Bulletin; February 1982, Vol. 31 Issue: 2 p317-320, 4p
Abstrakt: 1.2-Acetyl-a-2,3-epoxycarane which exists in solution as a single gauche conformer with minimal polarity was synthesized by the epoxidation of 2-acetyl-2-carene by perphthalic acid.2.The conjugation in the system of double bonds in 2-acetyl-2-carene is disturbed due to acoplanarity of the C=C-C=O fragment.
Databáze: Supplemental Index