Structure of asymmetric clusters that carry out enantioselective heterogeneous catalysis

Autor: Vedenyapin, A. A., Klabunovskii, E. I., Vlasenko, Yu. V.
Zdroj: Russian Chemical Bulletin; November 1981, Vol. 30 Issue: 11 p2083-2086, 4p
Abstrakt: Conclusions 1.The IR spectra have been obtained of RR-(+)-tartaric acid chemisorbed on Cu, Ni, and Cu-Ni catalysts supported on Aerosil.2.We have considered the probable structure of the asymmetric clusters that carry out asymmetric hydrogenation, and of the intermediate heteroligand complexes through which the enantioselective reaction proceeds.
Databáze: Supplemental Index