Reaction of phosphorous acid esters with α-fluorocarbonyl compounds
| Autor: | Kibardin, A. M., Gazizov, T. Kh., Gryaznov, P. I., Pudovik, A. N. |
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| Zdroj: | Russian Chemical Bulletin; May 1981, Vol. 30 Issue: 5 p855-857, 3p |
| Abstrakt: | 1.The reaction of trimethyl phosphite with fluoral proceeds with the formation of a mixture of 2,2,2-trimethoxy-3,5-bis(trifluoromethyl)-1,4,2-dioxaphospholane, trimethyl phosphate, and dimethyl methylphosphonate.2.The reaction of diethyl trimethylsilyl phosphite with fluoral gives diethyla-trimethylsiloxy-ß,ß,ß-trifluoroethylphosphonate, which at an elevated temperature decomposes to diethylß,ß-difluorovinyl phosphate. |
| Databáze: | Supplemental Index |
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