IR-spectroscopic investigation of the protonation of N-methylethylenimine by the H3O+ cation with the aid of low-temperature matrix isolation

Autor:	Lebedeva, T. L., Avakyan, V. G., Zhuk, D. S.
Zdroj:	Russian Chemical Bulletin; January 1981, Vol. 30 Issue: 1 p85-88, 4p
Abstrakt:	1.The direct observation of the protonation of an imine by the hydronium ion in the example of the N-methylethylenimine (MEI)-H3O+·Cl- system has been carried out.2.It has been shown experimentally that the protonation of a hydrated imine also takes place for MEI·H2O despite the fact that the lone pair of the N atom is shielded by an H bond, i.e., the water participating in the formation of the hydrate does not prevent protonation.
Databáze:	Supplemental Index
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