| Autor: |
Salomatin, G. I., Sobolevskii, V. S., Lafer, L. I., Yakerson, V. I. |
| Zdroj: |
Russian Chemical Bulletin; September 1980, Vol. 29 Issue: 9 p1405-1410, 6p |
| Abstrakt: |
Conclusions 1.Upon adsorption of formic acid on?-Al2O3, besides the formation of formate ions, chemisorption of HCOOH to Lewis-acid centers associated with the protonation of the hydroxyl of the carboxylic group also occurs.2.Treatment of the surface of reduced inserted copper with water vapor or a mixture of CO and H2O leads to a change in the state of the formate formed by the chemisorption of HCOOH.3.Under identical treatment conditions of the reduced copper surface with a mixture of CO and H2O, the compounds formed during adsorption of this mixture or HCOOH have similar structures and are represented as surface formate ions. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
Full text from SpringerLink