Catalysts for the hydrogenation of dehydro(acetylamino acids) based on palladium and rhodium complexes of bissalicylidene derivatives of diamines

Autor: Baryshnikov, A. T., Belikov, V. M., Latov, V. K., Saporovskaya, M. B.
Zdroj: Russian Chemical Bulletin; July 1981, Vol. 30 Issue: 7 p1206-1209, 4p
Abstrakt: Summary 1.Complexes of palladium and rhodium with bissalicylidene derivatives of ethylenediamine, propanediamine, and cyclohexanediamine have been obtained which possess catalytic activity in the hydrogenation of dehydro(acetylamino acids).2.The complexes of palladium and rhodium containing derivatives of chiral diamines are capable of catalyzing the enantioselective hydrogenation of dehydro(acetylamino acid)s.
Databáze: Supplemental Index