The hydroboration of 3-methylbicylo[4.1.0]hept-3-ene

Autor: Kazakova, É. Kh., Isaeva, Z. G., Bikeev, Sh. S.
Zdroj: Russian Chemical Bulletin; October 1979, Vol. 28 Issue: 10 p2151-2155, 5p
Abstrakt: 1.A mixture of two stereoisomers of 3-methylbicyclo[4.1.0]heptan-4-ol in 9:1 ratio was formed in the oxidative hydroboration of 3-methylbicyclo[4.1.0]hept-3-ene.2.3-Methylbicyclo[4.1.0]heptan-4-ones under epimerization conditions yield an equilibrium mixture of cis and trans isomers in 2:3 ratio.
Databáze: Supplemental Index
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