Electrochemical oxidation of aliphatic polynitro compounds. 3. Certain reactions of electrochemically generated trinitromethyl radicals

Autor: Pal'mbakh, G. G., Kokorekina, V. A., Shevelev, S. A., Feoktistov, L. G., Fainzil'berg, A. A.
Zdroj: Russian Chemical Bulletin; August 1979, Vol. 28 Issue: 8 p1569-1572, 4p
Abstrakt: 1.Trinitromethyl radicals generated electrochemically on the Pt electrode are capable of detaching hydrogen atoms from substrates such as acetonitrile, toluene, benzyl chloride, cyclohexane, and diethyl ether; fragmentation of the TNM radical into inorganic compounds predominates when hydrogen detachment is either impossible or hindered.2.Detachment of halogen atoms from halogen-containing organic substrates, and addition of the TNM radicals to diene and their recombination with intermediate alkyl radicals, all take place here, but only to a limited degree.
Databáze: Supplemental Index
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