Monomerization of dicyclopentadiene and hydrogenation of cyclopentadiene in a stream of methane over palladium-ruthenium alloy

Autor: Ermilova, M. M., Basov, N. L., Smirnov, V. S., Rumyantsev, A. N., Gryaznov, V. M.
Zdroj: Russian Chemical Bulletin; August 1979, Vol. 28 Issue: 8 p1633-1635, 3p
Abstrakt: 1.Methane can be used as a heat-transfer agent for the monomerization of dicyclopentadiene and as carrier gas for the hydrogenation of cyclopentadiene (CPD) to cyclopentene at membrane catalysts consisting of a palladium alloy with 9.8% of ruthenium.2.Increases in the selectivity and in the yield of cyclopentene were found during hydrogenation of CPD with hydrogen passing through the membrane catalyst compared with the delivery of a mixture of CPD vapor and hydrogen at the same catalyst.
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