| Autor: |
Minachev, Kh. M., Avaev, V. I., Shpiro, E. S., Ryashentseva, M. A., Antoshin, G. V. |
| Zdroj: |
Russian Chemical Bulletin; December 1978, Vol. 27 Issue: 12 p2413-2419, 7p |
| Abstrakt: |
1.The hydrogenation of benzene by high-pressure H2 on 5% Re/?-Al2O3 and Re/SiO2 catalysts which have been reduced by the reaction mixture is zeroth order with respect to the benzene.2.The kinetics of the hydrogenation of benzene on the 5% Re/?-Al2O3 catalyst is not affected by the type of Re7+ compound used for preparing the catalyst. The reaction order with respect to H2 is approximately 2, and the apparent activation energy 10–11 kcal/mole.3.Passage from Re7+ to Re(0) is apparently a necessary condition for the activation of supported Re catalysts. The supported Re7+ can be effectively reduced by the C6H6-H2 mixture at 200°C. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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