| Autor: |
Yashin, A. I., Tinyakova, E. I., Bryantseva, Yu. V., Miesserov, K. G., Makhdi, V., Dolgoplosk, B. A. |
| Zdroj: |
Russian Chemical Bulletin; July 1978, Vol. 27 Issue: 7 p1404-1410, 7p |
| Abstrakt: |
Conclusions 1.The reaction of NiCl2 and CoCl2 with Al(i-Bu)3 in the presence of small amounts of dienes has been studied.2.The reaction of NiCl2 with Al(i-Bu)3 in the presence of a diene results in the formation ofp-alkylnickel chlorides, in which the alkenyl ligand contains an oligomer of the diene and an H atom or an isobutyl group, with yields of ~ 100%. The compounds synthesized are fairly stable with respect to deoxygenated water and aqueous solutions of HCl and H2SO4 and do not undergo disproportionation reactions.3.The reaction of CoCl2 with Al(i-Bu)3 in the presence of 1,3-pentadiene results in the predominant formation of organocobalt compounds which do not contain chlorine and which are less stable with respect to deoxygenated water and aqueous solutions of acids. |
| Databáze: |
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| Externí odkaz: |
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