A mass spectroscopic study of compounds from the cyclopropane series. 3. Behavior of alkoxy- and aryloxy-gem-dichlorocyclopropanes under electron impact

Autor:	Kadentsev, V. I., Tetushkina, T. K., Chizhov, O. S., Shostakovskii, S. M., Petinskii, A. A.
Zdroj:	Russian Chemical Bulletin; February 1978, Vol. 27 Issue: 2 p319-325, 7p
Abstrakt:	1.The principal direction of alkoxy-gem-dichlorocyclopropane M+ ion breakdown is that leading to the formation of gem-dichlorocyclopropyl ions, and the alkyl ions resulting from their decomposition, together with rearranged fragments with m/e 90, 91.2.Under electron impact, the aryloxy-gem-dichlorocyclopropanes give aromatic gem-dichlorocyclopropyl fragments, together with the ions, ArO+, ArO+, [M-Cl]+, [M-Cl, -CO]+, and [M-Cl, -HCl, -CO]+ ions.3.Conditions favoring and inhibiting these various processes have been given.
Databáze:	Supplemental Index
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