Reaction of 1,5-hydride shift in acylation of propyne by cis and trans isomers of 2-methylcyclohexanoyl tetrafluoroborate

Autor: Kanishchev, M. I., Smit, V. A., Shchegolev, A. A., Caple, R.
Zdroj: Russian Chemical Bulletin; January 1978, Vol. 27 Issue: 1 p215-218, 4p
Abstrakt: Conclusions The reaction of propyne with the cis and trans isomers of 2-methylcyclohexanoyl tetrafluoroborate proceeds with the formation of the products of 1,5-hydride shift, in which connection its direction depends on the configuration of the reagent.
Databáze: Supplemental Index