The asymmetric hydrogenation ofα-acetoaminocinnamic acid and its ester on triphenylphosphinato-d-α-methylbenzylamminatorhodium(I)

Autor: Samoilenko, L. M., Latov, V. K., Belikov, V. M.
Zdroj: Russian Chemical Bulletin; June 1977, Vol. 26 Issue: 6 p1216-1219, 4p
Abstrakt: Conclusions The interaction of d-a-methylbenzylamine with the chloride of tris(triphenylphoshpine)-rhodium(I) in an atmosphere of hydrogen leads to the formation of mixed chiral complex catalysts for the asymmetric hydrogenation ofa-acetoaminocinnamic acid and its methyl ester to phenylanoline.
Databáze: Supplemental Index