| Autor: |
Nesmeyanov, A. N., Perevalova, E. G., Leont'eva, L. I., Shumilina, E. V. |
| Zdroj: |
Russian Chemical Bulletin; May 1977, Vol. 26 Issue: 5 p1048-1052, 5p |
| Abstrakt: |
Conclusions 1.The Fe-C s bond in s-cymantrenyl(p-cyclopentadienyl)dicarbonyliron is more resistant to the action of mercury salts, iodine, and hydrochloric acid than those in the s-phenyl and s-ferrocenyl derivatives.2.The reaction of the sodium salt of p-cyclopentadienyldicarbonyliron with cymantrenoyl chloride yielded the s-cymantrenoyl derivative of p-cyclopentadienyldicarbonyliron.3.The replacement of one CO group on the iron atom in the s-cymantrenyl and s-cymantrenoyl complexes of p-cyclopentadienyldicarbonyliron by triphenylphosphine has been effected.4.Decarbonylation of the s-cymantrenoyl derivatives C5H5(CO)LFe-COC5H4,Mn(CO)3 (L = CO and PPh3) to the corresponding s-cymantrenyl derivatives C5H5(CO)LFe-C5H4,Mn(CO)3 has been carried out. |
| Databáze: |
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