| Autor: |
Zgonnik, V. N., Sergutin, V. M., Kalnin'sh, K. K., Lyubimova, G. V., Nikolaev, N. I. |
| Zdroj: |
Russian Chemical Bulletin; April 1977, Vol. 26 Issue: 4 p709-713, 5p |
| Abstrakt: |
Conclusions 1.Butyllithium (BL) forms 4:1 and 4:2 complex with trimethylamine (TMA). A 4:4 complex is observed in isooctane solution at temperature below -70°C. With an excess of BL and at low temperature, disproportionation reactions lead to the formation of 4:4 and 6:1 complexes.2.Butyllithium forms 4:1 and 4:2 complexes with triethylamine. These complexes are less stable than the corresponding BL-TMA complexes.3.The mixed complexes of BL with TMA and TEA have been characterized. Butyllithium coordinates more firmly with THF than with TMA. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
Full text from SpringerLink