Participation of Cu(III) in copper sulfate-catalyzed oxidation of 3-carboxypropyl radicals with S2O82− ions

Autor: Ogibin, Yu. N., Troyanskii, É. I., Starostin, E. K., Moryasheva, S. I., Nikishin, G. I.
Zdroj: Russian Chemical Bulletin; April 1977, Vol. 26 Issue: 4 p859-862, 4p
Abstrakt: Conclusions A mechanism was proposed for the selective oxidative cyclization of 3-carboxyprqpyl radicals to ?-butyrolactone when using the Na2S2O8-CuSO4 oxidation system. In this mechanism the Cu(III) ions take part in the reaction.
Databáze: Supplemental Index