Catalytic and asymmetrizing activity of mixed copper-nickel catalysts, deposited on aerosil, in the hydrogenation of acetylacetone
Autor: | Vlasenko, Yu. V., Klabunovskii, E. I., Vedenyapin, A. A., Brezzhunova, L. N., Rubtsov, I. A. |
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Zdroj: | Russian Chemical Bulletin; March 1977, Vol. 26 Issue: 3 p616-618, 3p |
Abstrakt: | Conclusions A mixed Cu-Ni (1:1) catalyst, deposited on aerosil and modified with D-(+)-tartarie acid, was obtained, which is active in theselective stereoselective hydrogenation of acetylacetone to the (-)-ketol. The optical yield of the ketol is 9.1% at 133°. |
Databáze: | Supplemental Index |
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