Catalytic and asymmetrizing activity of mixed copper-nickel catalysts, deposited on aerosil, in the hydrogenation of acetylacetone

Autor: Vlasenko, Yu. V., Klabunovskii, E. I., Vedenyapin, A. A., Brezzhunova, L. N., Rubtsov, I. A.
Zdroj: Russian Chemical Bulletin; March 1977, Vol. 26 Issue: 3 p616-618, 3p
Abstrakt: Conclusions A mixed Cu-Ni (1:1) catalyst, deposited on aerosil and modified with D-(+)-tartarie acid, was obtained, which is active in theselective stereoselective hydrogenation of acetylacetone to the (-)-ketol. The optical yield of the ketol is 9.1% at 133°.
Databáze: Supplemental Index