Preparation and certain physicochemical properties of complexes of nickel(II) and copper(II) with N-salicylideneaminopyridinium iodide

Autor:	Troepol'skaya, T. V., Tkachenko, E. L., Munin, E. N., Kitaev, Yu. P.
Zdroj:	Russian Chemical Bulletin; January 1977, Vol. 26 Issue: 1 p1-3, 3p
Abstrakt:	1.Complexes of Cu(II) and Ni(II) with N-salicylideneaminopyridinium iodide, which have not been previously described, have been synthesized.2.By physicochemical methods it is shown that the complexes are chelate with the composition 1:2 (of metal and aldehyde residue of ligands deprotonized at the OH group).3.Their electrochemical behavior in DMFA on a dropping mercury electrode is studied and it is shown that it is due to discharge of all the particles of the complex; the first electron is taken up at a low vacant orbital with mixed metal-ligand character.
Databáze:	Supplemental Index
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