Comparison of kinetic data with the results of quantum-chemical calculations on intramolecular rupture of the o-carboxyamide bond

Autor: Nechaev, P. P., Mukhina, O. A., Kosobutskii, V. A., Belyakov, V. K., Vygodskii, Ya. S., Moiseev, Yu. V., Zaikov, G. E.
Zdroj: Russian Chemical Bulletin; August 1977, Vol. 26 Issue: 8 p1615-1619, 5p
Abstrakt: 1.Study has been made of the kinetics of the intramolecular breakdown of five N-substituted phthalamic acids, and quantum-chemical calculations carried out on their respective molecules, working through the semi-empirical PPP method.2.A mechanism of the intramolecular rupture of the o-carboxyamide bond has been proposed on the basis of our kinetic data and the results of the quantum-chemical calculations.
Databáze: Supplemental Index