Autor: |
Matrosov, E. I., Kozachenko, A. G., Kabachnik, M. I. |
Zdroj: |
Russian Chemical Bulletin; July 1976, Vol. 25 Issue: 7 p1406-1410, 5p |
Abstrakt: |
1.Determination of base pKa's in nonaqueous solution by potentiometric titration is discussed, the case considered being that in which base protonization is masked by BHB+ complex formation and incomplete salt (ion pair) dissociation.2.Using a new nitromethane pH scale based on picrate buffers, pKa (CH3NO2) values for various azobases have been determined from potentiometric titration data. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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