Acid-base interactions in nitromethane

Autor: Matrosov, E. I., Kozachenko, A. G., Kabachnik, M. I.
Zdroj: Russian Chemical Bulletin; July 1976, Vol. 25 Issue: 7 p1406-1410, 5p
Abstrakt: 1.Determination of base pKa's in nonaqueous solution by potentiometric titration is discussed, the case considered being that in which base protonization is masked by BHB+ complex formation and incomplete salt (ion pair) dissociation.2.Using a new nitromethane pH scale based on picrate buffers, pKa (CH3NO2) values for various azobases have been determined from potentiometric titration data.
Databáze: Supplemental Index