Free-radical addition of alcohols to α, β- unsaturated acids under high pressure

Autor:	Nikishin, G. I., Spektor, S. S., Shakhovskoi, G. P., Glukhovtsev, V. G., Zhulin, V. M.
Zdroj:	Russian Chemical Bulletin; July 1976, Vol. 25 Issue: 7 p1579-1581, 3p
Abstrakt:	1.The radical-chain process for the formation of ?-lactones from alcohols andß-alkyl-substituteda, ß-unsaturated acids is accelerated substantially with increase in the pressure.2.Sterically hindered reactions, which practically do not go under ordinary conditions, can be run at a pressure of 10,000 kgf/cm2 to give ?-lactones in a preparative yield.
Databáze:	Supplemental Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink