Mass-spectrometric determination of the 4-center configuration in trans-linked 1,4-dialkyldecahydroquinolol-4′s

Autor: Zaikin, V., Smetanin, V., Vul'fson, N., Akhrem, A., Ukhova, L., Kukso, G.
Zdroj: Russian Chemical Bulletin; July 1976, Vol. 25 Issue: 7 p1452-1455, 4p
Abstrakt: By studying molecular ion stabilities and values of the $$I_{[M - C_2 H_5 ]^ + } /I_{[M]^ + } $$ ratio (the [M-C2H5]+ results from 4-C2H5 group elimination), we have been led to 4-center configurations for the trans-linked 1-alkyl-4-ethyl(ethynyl)decahydroquinolol-4′s (Alk=CH3, C2H5, n-and i-C3H7).
Databáze: Supplemental Index
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