Production of cesium hexaperchloratotitanate by the reaction of titanium perchlorate with cesium perchlorate

Autor:	Babaeva, V. P., Rosolovskii, V. Ya.
Zdroj:	Russian Chemical Bulletin; November 1975, Vol. 24 Issue: 11 p2278-2281, 4p
Abstrakt:	1.Titanium perchlorate in anhydrous perchloric acid medium with the formation of cesium hexaperchloratotitanate Cs2 [Ti(ClO46)]. Complexes with a ratio CsClO4:Ti(ClO4)4>2 are not formed.2.On the basis of the IR spectra, a conclusion was drawn on a change in the mode of coordination of the perchlorato groups from bidentate in the Ti(ClO4)4 molecule to monodentate in the [Ti(ClO4)6]2- anion.
Databáze:	Supplemental Index
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