Cleavage of o-carboranes to (3)-l,2-dicarbaundecarborates by amines

Autor: Zakharkin, L. I., Kirillova, V. S.
Zdroj: Russian Chemical Bulletin; November 1975, Vol. 24 Issue: 11 p2484-2486, 3p
Abstrakt: When the cleavage rate of some C-substituted o-carboranes to the (3)-l,2-dicarbaunde-carborate anion by treatment with amines was studied it was established that the reaction is first order in both the o-carborane and the amine. The cleavage rate depends on the nature of the amine and the nature of the substituent in the o-carborane.
Databáze: Supplemental Index