Reaction of triphenylgermanium and triphenylsilicon hydroperoxides with isocyanic acid

Autor: Surova, R. P., Muraeva, N. P., Druzhkov, O. N., Lapshin, N. M., D'yachkovskaya, O. S.
Zdroj: Russian Chemical Bulletin; July 1975, Vol. 24 Issue: 7 p1516-1518, 3p
Abstrakt: 1.The triphenylgermanium and triphenylsilicon hydroperoxides react with isocyanic acid with cleav age of the E-O bond and the formation of the triphenylgermanium and triphenylsilicon isocyanates and hydrogen peroxide.2.Intramolecular rearrangement of the starting molecule also occurs in the case of triphenylsilicon hydroperoxide, with migration of the phenyl group to the hydroperoxide oxygen.3.Hydrogen peroxide reacts with isocyanic acid to give the previously unknown carbamoyl peroxide, which in the solid phase decomposes at 50° to CO2 and the hydroxyurea isomer.
Databáze: Supplemental Index
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