| Autor: |
Zverev, V. V., Vilesov, F. I., Vovna, V. I., Lopatin, S. N., Kitaev, Yu. P. |
| Zdroj: |
Russian Chemical Bulletin; May 1975, Vol. 24 Issue: 5 p961-966, 6p |
| Abstrakt: |
1.The photoelectronic spectra of a number of organophosphorus compounds of the type of WPXYZ were obtained and interpreted for the first time.2.The upper orbital is primarily localized on the pp-orbitals of the W atom, participates in the bonding of WP, and has little conjugation with the orbitals of the unshared pairs of the substituents. Exceptions are nitrogen-containing substituents.3.Series of atoms W with respect to decreasing influence on the ionization potentials of the UEP of the substituents XYZ were established: for nonnitrogen-containing substituents OP > SP > P, and for nitrogen-containing substituents SP > OP > P. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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