Spectral and polarographic characteristics of certain N-(2-hydroxyethyl) alkylidenamines

Autor: Dmitrieva, Z. T., Skorokhodova, T. S., Polyakova, L. G., Velikova, T. M., Bel'skii, I. F.
Zdroj: Russian Chemical Bulletin; April 1975, Vol. 24 Issue: 4 p709-714, 6p
Abstrakt: 1.A series of N-(2-hydroxyethyl) alkylidenamines (HEA) was produced by the condensation of ethanolamine with ketones.2.The frequency of the C=N valence vibration in the IR spectra of HEA depends little on the electronic structure of C, N-substituents.3.According to the data of the PMR spectra, HEA exists in two configurations (syn- and anti-isomers).4.The polarographic reduction of HEA was studied; a dependence of the half-wave potential on the existence of an intramolecular hydrogen bond is observed.
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