Synthesis and properties of triferrocenylphosphine oxide

Autor: Nesmeyanov, A. N., Vil'chevskaya, V. D., Krylova, A. I., Nekrasov, Yu. S., Tolkunova, V. S.
Zdroj: Russian Chemical Bulletin; March 1975, Vol. 24 Issue: 3 p635-636, 2p
Abstrakt: 1.Triferrocenylphosphine was oxidized to triferrocenylphosphine oxide by reaction with MnO2, KMnO4, or with atmospheric oxygen on aluminum oxide.2.The stable complex Fc3PO ·HgCl2, where Fc = -C5H4FeC5H5, was obtained. The Fc3PO complexes with benzene easily cleave the complex-bound benzene by heating in xylene.
Databáze: Supplemental Index