Complexes of tetrabutylammonium aluminum hydride with diborane

Autor: Titov, L. V., Sasnovskaya, V. D., Rosolovskii, V. Ya.
Zdroj: Russian Chemical Bulletin; November 1974, Vol. 23 Issue: 11 p2326-2329, 4p
Abstrakt: 1.Compounds with complex anions AlH4-n(BH4)n-, where n = 1, 2, 3, were produced by the reaction of tetrabutylammonium aluminum hydride with a measured amount of diborane; their melting points were determined, and their IR spectra taken.2.The decomposition of Bu4NAlH4-n(BH4)n in THF and diethyl ether medium was studied. The rate of decomposition of the complexes in THF solution increases with increasing number of coordinated BH4 groups.
Databáze: Supplemental Index