Reaction of thiodiacetone alcohol with chlorides of trivalent phosphorus acids
| Autor: | Rizpolozhenskii, N. I., Stepashkina, L. V., Eliseenkova, R. M. |
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| Zdroj: | Russian Chemical Bulletin; September 1974, Vol. 23 Issue: 9 p2039-2041, 3p |
| Abstrakt: | 1.Thiodiacetone alcohol reacts with the monochlorides of trivalent phosphorus acids in the presence of a base to give tricoordinated phosphorus derivatives. 2-Ethoxy-2-thio-3,5,5-trimethyl-1,2-thia-3-phos-pholanol is formed in the case of ethyl dichlorophosphite.2.The reaction of thiodiacetone alcohol with phenyldichlorophosphine in the absence of a base gives 2-phenyl-2-thio-1,2-oxa-3,3,5-trimethyl-4-phospholene. |
| Databáze: | Supplemental Index |
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