Reaction of succinonitrile with aliphatic amines

Autor: Keppen, V. A., Andronov, V. N., Andreeva, M. A., Karysheva, V. M., Zhuk, D. S.
Zdroj: Russian Chemical Bulletin; December 1973, Vol. 22 Issue: 12 p2655-2658, 4p
Abstrakt: The reaction of primary amines with succinonitrile leads to the formation of N,N,N',N'-tetrasubstituted amidines and the liberation of 2 M of NH3. The reaction of secondary amines with succinonitrile proceeds as an intramolecular condensation with the liberation of 1 M of NH3 per mole of the dinitrile and the formation of the ?2,5-a, a'-dialkylaminopyrrolene.
Databáze: Supplemental Index