Esters of trivalent phosphorus thioacids

Autor: Eliseenkova, R. M., Rizpolozhenskii, N. I., Akamsin, V. D.
Zdroj: Russian Chemical Bulletin; December 1973, Vol. 22 Issue: 12 p2687-2690, 4p
Abstrakt: 1.The reaction of S-alkyl alkyl(aryl)chlorothiophosphonites with propargyl alcohol or with propargyl mercaptan in the presence of a base leads to the formation of S-alkyl alkyl(aryl)allenylthio(dithio)phosphinates, which when heated with a sodium alcoholate are converted to S-alkyl alkyl(aryl)-1-propynylthiophosphinates.2.Alkyl(aryl)dichlorothiophosphites react with propargyl alcohol to give S-alkyl(aryl)allenylchlorothiophosphonates, while the reaction of ethyldichlorophosphine with propargyl mercaptan leads to the formation of ethylallenylchlorothionophosphine.
Databáze: Supplemental Index