Isomeric transformations of nitrocinnamic ester

Autor: Babievskii, K. K., Belikov, V. M., Filatova, I. M., Garbalinskaya, N. S.
Zdroj: Russian Chemical Bulletin; July 1973, Vol. 22 Issue: 7 p1556-1558, 3p
Abstrakt: 1.We studied the thermal isomerization ofa-nitrocinnamic ester, and also its isomerization by treatment with certain polar solvents with a basic character. The composition of the obtained equilibrium mixture of geometric isomers is independent of the method of isomerization.2.The reaction for the nucleophilic addition of methyl alcohol to the Z-isomer ofa-nitrocinnamic ester is accompanied by its isomerization to the E-isomer.
Databáze: Supplemental Index