Migration of alkylthio group during cleavage of thiols from 1,1,3-tris (alkylthio) propanes

Autor: Atavin, A. S., Mikhaleva, A. I., Pestunovich, V. A., Chebotareva, E. G., Kaigorodova, V. I., Trofimov, B. A.
Zdroj: Russian Chemical Bulletin; October 1973, Vol. 22 Issue: 10 p2276-2278, 3p
Abstrakt: Conclusions 1.1,3-Di (alklythio)-1-propenes are formed predominantly when alkanethiols are cleaved from 1,1,3tris(alkylthio)propanes in the presence of diethyl phosphite or potassium tert-butoxide.2.The elimination is accompanied by migration of the alkylthio group, and leads to the formation of 1,2-di(alkylthio)-1-propenes.
Databáze: Supplemental Index