Investigation of the hydrogenation of p-carboxybenzaldehyde in the presence of Pd-, Ru-, and Rh -catalysts

Autor:	Freidlin, L. Kh., Litvin, E. F., Gurskii, R. N., Oparina, G. K., Istratova, R. V.
Zdroj:	Russian Chemical Bulletin; August 1972, Vol. 21 Issue: 8 p1682-1685, 4p
Abstrakt:	1.The hydrogenation of p-carboxybenzaldehyde proceeds according to zero order with respect to the substrate and according to first order with respect to H2.2.On Pd-catalysts, hydrogenation is accompanied by subsequent hydrogenolysis of the C-OH bond of the carbinol formed.3.On a Rh-catalyst hydrogenolysis proceeds extremely slowly, while on a Ru-catalyst p-carboxy-benzyl alcohol is selectively formed.
Databáze:	Supplemental Index
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