Effect of unsymmetrical substitution on the nuclear quadrupole resonance spectra of trivalent antimony

Autor: Semin, G. K., Bryukhova, E. V., Babushkina, T. A., Svergun, V. I., Borisov, A. E., Novikova, N. V.
Zdroj: Russian Chemical Bulletin; May 1972, Vol. 21 Issue: 5 p1134-1135, 2p
Abstrakt: Very strong asymmetrization of the electron distribution on the central atom occurs for the unsymmetrically substituted compounds of trivalent antimony, which is expressed in a noticeable increase of the asymmetry parameter and the constants of the quadrupole bond for121Sb and123Sb when compared with compounds of the SbX3 type.
Databáze: Supplemental Index