Autor: |
Zabelaite, V. A., Stumbrevichute, Z. A., Rasteikene, L. P., Lin'kova, M. G., Knunyants, I. L. |
Zdroj: |
Russian Chemical Bulletin; October 1971, Vol. 20 Issue: 10 p2140-2143, 4p |
Abstrakt: |
1.The addition of methylsulfenyl chloride to dimethylacrylic acid derivatives initially leads to the formation of the unstablea-chloro-ß-methylmercapto derivatives, which are very easily isomerized to the stableß-chloro-a-methylmercapto derivatives of isovaleric acid.2.The derivatives ofß-chloro-a-methylmercaptoisovaleric acid, in contrast to the derivatives ofß-chloro-ß-methylmercaptopropionic acid, do not cleave hydrogen chloride when treated with triethylamine. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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