Some properties of cesium perchloratoborate

Autor: Rosolovskii, V. Ya., Babaeva, V. P.
Zdroj: Russian Chemical Bulletin; April 1971, Vol. 20 Issue: 4 p792-794, 3p
Abstrakt: 1.The boron atom is capable of coordinating four perchlorato groups with the formation of the complex anion [B(ClO4)4]-.2.The properties of cesium perchloratoborate were studied. The low heat stability of Cs[B(ClO4)4] is explained by the substantial deviation in the symmetry of the ClO4 groups from tetrahedral and a weakening of the Cl-O(B) bonds.
Databáze: Supplemental Index