Lability of hydrogen atoms in the methyl group of some methyl ketones of the cene and arene series

Autor:	Setkina, V. N., Kislyakova, N. V., Kolobova, N. E., Kursanov, D. N.
Zdroj:	Russian Chemical Bulletin; April 1971, Vol. 20 Issue: 4 p751-753, 3p
Abstrakt:	1.A study was made of the kinetics of the isotopic hydrogen exchange of the methyl groups of acetylcyclopentadienylrhenium tricarbonyl and acetophenonechromium tricarbonyl with deuteroethanol in the presence of potassium hydroxide.2.On the basis of these data, and the data previously obtained by us, was constructed a sequence, characterizing the electronic effect of cene and arene moieties on the activity of the protons of the corresponding methyl ketones.
Databáze:	Supplemental Index
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