Substituted bicyclic phospholanes

Autor: Khairullin, V. K., Dmitrieva, G. V., Pudovik, A. N.
Zdroj: Russian Chemical Bulletin; June 1971, Vol. 20 Issue: 6 p1155-1158, 4p
Abstrakt: 1.The corresponding adducts of the diene synthesis reaction were obtained as the result of the reaction of 2-ethyl-2,5-dioxo-1,2-oxa-3-phospholene and 3-methyl-2-ethyl-2,5-dioxo-1,2-oxa-3-phospholene with 2,3-dimethyl-1,3-butadiene.2.The alcoholysis of 5,6-dimethyl-1-ethyl-1,3-dioxo-2-oxa-1-phosphabicyclo[3,0,4]-5,6-nonene proceeds contrary to the Pearson rule, with the alcohol attacking the carbon of the carbonyl group.
Databáze: Supplemental Index