Synthesis of 2-o-(2-acetamido-2-deoxy-β-d-glucopyranosyl) glycerol and 2-acetamido-3-o-(2-acetamido-2-deoxy-β-d-glucopyranosyl)-2-deoxy-d-glucopyranose using the oxazoline method
Autor: | Antonenko, T. S., Zurabyan, S. É., Khorlin, A. Ya. |
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Zdroj: | Russian Chemical Bulletin; May 1970, Vol. 19 Issue: 5 p1086-1088, 3p |
Abstrakt: | Conclusions A description is forwarded of the synthesis of 2-O-(2-acetamido-2-deoxy-ß-D-glucopyranosyl)glycerol and 2-acetamido-3-0-(2-acetamido-2-deoxy-ß-D-glucopyranosyl)-2-deoxy-ß-D-glucopyranose by glycosylation of 1,3-O-benzylideneglycerol and benzyl-2-acetamido-4,6-benzylidene-2-deoxy-ß-D-glucopyranoside, respectively, by 2-methyl-4,5-(3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyrano)-?2-oxazoline with subsequent elimination of the protective radicals. |
Databáze: | Supplemental Index |
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