Synthesis of 2-o-(2-acetamido-2-deoxy-β-d-glucopyranosyl) glycerol and 2-acetamido-3-o-(2-acetamido-2-deoxy-β-d-glucopyranosyl)-2-deoxy-d-glucopyranose using the oxazoline method

Autor: Antonenko, T. S., Zurabyan, S. É., Khorlin, A. Ya.
Zdroj: Russian Chemical Bulletin; May 1970, Vol. 19 Issue: 5 p1086-1088, 3p
Abstrakt: Conclusions A description is forwarded of the synthesis of 2-O-(2-acetamido-2-deoxy-ß-D-glucopyranosyl)glycerol and 2-acetamido-3-0-(2-acetamido-2-deoxy-ß-D-glucopyranosyl)-2-deoxy-ß-D-glucopyranose by glycosylation of 1,3-O-benzylideneglycerol and benzyl-2-acetamido-4,6-benzylidene-2-deoxy-ß-D-glucopyranoside, respectively, by 2-methyl-4,5-(3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyrano)-?2-oxazoline with subsequent elimination of the protective radicals.
Databáze: Supplemental Index