The use of gas chromatography to separate aliphatic unsaturated sulfur-containing compounds

Autor: Prilezhaeva, E. N., Shekhtman, R. I., Rudenko, B. A., Snegotskii, V. I., Laba, V. I.
Zdroj: Russian Chemical Bulletin; September 1970, Vol. 19 Issue: 9 p1831-1834, 4p
Abstrakt: 1.The conditions of high-temperature gas chromatography of substances containing sulfur simultaneously in the form of sulfide and sulfone groups in conjunction with a double bond on filled columns with an efficiency of 4500–5000 theoretical plates were developed.2.The quantitative results obtained with a flame-ionization detector in the chromatography of isomeric sulfur-containing compounds correspond to the true composition of the mixture to be analyzed.3.The separation of cis- and trans-isomers of ethyl-ß-bromovinyl sulfides by the method of preparative gas chromatography was accomplished for the first time.
Databáze: Supplemental Index