Influence of steric factors on the electrochemical reduction of bromo-derivatives of 7-oxabicyclo-[2,2,1]heptane

Autor: Butin, K. P., Belokoneva, N. A., Eldikov, V. N., Zefirov, N. S., Beletskaya, I. P., Reutov, O. A.
Zdroj: Russian Chemical Bulletin; February 1969, Vol. 18 Issue: 2 p214-217, 4p
Abstrakt: 1.The influence of the steric position of the bromine atom on the parameters of the polarographic reduction of certain bromo-derivatives of 7-oxabicyclo[2,2,l]heptane was considered.2.Bromine in the exo-position is reduced more readily than bromine in the endo-position. The reduction of vicinal dibromides, bromohydrins, and acetylbromohydrins apparently occurs according to a 1,2-elimination mechanism.
Databáze: Supplemental Index