| Autor: |
Bartok, M., Kozma, B., Shuikin, N. I. |
| Zdroj: |
Russian Chemical Bulletin; January 1968, Vol. 17 Issue: 1 p123-126, 4p |
| Abstrakt: |
1.The thermal conversions of 3-monoalkyl-substitutedß-oxides were investigated, using a microreactor mounted in a chromatograph.2.In the thermal decomposition of this type ofß-oxides, there are two primary processes. The main direction of the reaction is decomposition of the molecules to formaldehyde and the corresponding olefins (~90%). In addition to decomposition, isomerization of theß-oxides and aldehydes (5–7%) was also observed; the formation of the latter may be explained by the influence of the walls of the microreactor.3.Secondary processes may include decarbonylation of the primary products. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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